The Spectroscopic and theoretical investigations of complex formation of (3E,3'E)-7,7'-(carbonylbis(azanediyl))bis(3-(2-(2-hydroxyphenyl)hydrazono)-4-oxo-3,4-dihydronaphthalene-2-sulfonic acid) with metal cations

  • Olga Kovalchukova Peoples' Friendship University of Russia
  • Mikhael Ryabov Peoples' Friendship university of Russia
  • Alexandra Obmenennaya A.N. Kosygin Russian State University (Technology. Design. Art)
  • Nikolai Popandopulo A.N. Kosygin Russian State University (Technology. Design. Art)
Keywords: Azodye, complex formation, UV-VIS spectroscopy, theoretical modeling, spatial and electronic structure

Abstract

A novel azo-dye  was isolated by a diazo-coupling reaction and characterized by the elemental analysis, mass spectra, IR and UV-VIS spectroscopy. The processes of complex formation of H4L with some mono-, bis-, and trivalent metal cations were studied by spectrophotometric titration and theoretical modeling. The NBO effective charge calculations indicate a strong covalent character of the coordination bonds at complexation.

Downloads

Download data is not yet available.

Author Biography

Mikhael Ryabov, Peoples' Friendship university of Russia

Dr, Department of General Chemistry

References

Elgemeie, G.E.H., Maher, H.H., Heba, M. Pigment & Resin Technology 30, 2001, p. 210.

Koh, J., Greaves, A.J. Dyes and Pigments, 50, 2001, p. 117.

Robert, T.M., Robert, N.B., Bhattacharjee, S.K. Organic Chemistry, 6th edition, New Delhi. Pearson Prentice Hall, 2011.

Zollinger, H. Color Chemistry. Syntheses, Properties, Application of Organic Dyes and Pigments, Third revised edition, Wiley-VCH, 2003.

Samieh, F., Ahmad, M.T., Hooshang, H., Hojatollah, K. ARKIVOC XIV, 2008, p. 115.

Kirkan, B., Gup, R. Turkey Journal of Chemistry, 32, 2008, p. 9.

Gregory, P.D., Waring, R., Hallas, G. The Chemistry and Application of Dyes, Plenum Press, London, 1990.

Katz, H.E., Singer, K.D., Sohn, J.E., Dirk, C.W., King, L.A., Gordon, H.M. Journal of the American Chemical Society, 109, 1987, p. 6561.

Li, X., Wu, Y., Gu, D., Gan, F. Dyes and Pigments, 86, 2010, p. 182.

Wang, S., Shen, S., Xu, H. Dyes and Pigments, 44, 2000, p. 195.

Gan, F.X., Hou, L.S., Wang, G.B., Liu, H.Y. Materials Science Engineering, B76, 2000, p. 63.

Chen, Y.Q., Wu, D.H., Gu, F.X. Dyes and Pigments, 76, 2008, p. 624.

Li, X.Y., Wu, Y.Q. Gu, D.H., Gan, F.X. Materials Science Engineering, B158, 2009, p. 53.

The Chemistry of Dyes - Azo Dyes / University of Bristol, School of Chemistry–URL: http://www.chm.bris.ac.uk/webprojects2002/price/azo.htm

Beck, M.T., Nadypal, I. Chemistry of complex equilibria, Akad. Kiado, Budapest, 1989.

Becke, A.D. Journal of Chemical Physics, 98, 1993, p. 5648.

Schaefer, A., Huber, C., Ahlrichs, R. Journal of Chemical Physics, 100, 1994, p. 5829.

Glendening, E.D., Badenhoop, J.K., Reed, A.E. “NBO 5.G,” Theoretical Chemistry Institute, University of Wisconsin, Madison, W I, 2004 http://www.chem.wisc.edu/~nbo5

Granovsky, A. “Firefly version 7.1.G,” http://classic.chem.msu.su/gran/firefly/index.html.

Published
2018-07-31
How to Cite
Kovalchukova, O., Ryabov, M., Obmenennaya, A., & Popandopulo, N. (2018). The Spectroscopic and theoretical investigations of complex formation of (3E,3’E)-7,7’-(carbonylbis(azanediyl))bis(3-(2-(2-hydroxyphenyl)hydrazono)-4-oxo-3,4-dihydronaphthalene-2-sulfonic acid) with metal cations. JOURNAL OF ADVANCES IN CHEMISTRY, 15(2), 6207-6217. https://doi.org/10.24297/jac.v15i2.7500
Section
Articles

Most read articles by the same author(s)