Chitosan Molecular Weight Effects on the Synthesis of Gold Nanoparticles and Catalytic Degradation of Environmental Pollutants

  • Hosam Salaheldin Ibrahim 1Department of Physics, Faculty of Science, Mansoura University, El-Gomhorya Street, 35516 Mansoura, Egypt
Keywords: Gold nanoparticles, Chitosan molecular weight, catalytic degradation, 4-nitrophenol, Methyl orange.

Abstract

Gold nanoparticles (Au NPs) was synthesized with Chitosan different molecular weight (MW) using  a microwave as a heating source. Since, Chitosan acts as a reducing and stabilizing agent. The as-synthesized Au NPs were characterized by transmission electron microscopy (TEM) images and selected area electron diffraction patterns (SAED). Furthermore, the Au NPs fabrication was ascertained by UV–Visible spectroscopy (UV–Vis) through the detection of the localized surface plasmon resonance (LSPR) characteristic peak, X-ray powder diffraction (XRD), and energy dispersive X-Ray Spectroscopy (EDS). The formation of the Au NPs was confirmed by the detection of a LSPR peak at 518–527 nm in the UV–Vis spectrum. In addition, the XRD studies depicted that the obtained Au NPs were highly crystalline with ‘face-centered’ cubic geometry. Moreover, TEM micrographs showed that the most Monodispersed AuNPs was synthesized with low molecular weight (LMW) Chitosan with particle size 4.48±0.09 nm. The synthesized Chitosan-Au nanocomposite exhibited an efficient catalytic property in the reduction of  two organic environmental pollutants which are, 4-nitrophenol (4-NP) and methyl orange (MO) dye in the presence of sodium borohydride (NaBH4).

Published
2018-06-04
Section
Articles